Cruciaromaticity in organometallic compounds

نویسندگان

  • Michael J. S. Dewar
  • Eamonn F. Healy
  • James Ruiz
چکیده

A recent suggestion, that transition metal complexes of unsaturated ligands can be regarded as cruciconjugated, is explored by studies of various complexes of Fe(II), the aromaticity of the resulting i systems being analyzed in terms of PMO theory. This approach is also applied to porphyrin. The conclusions are supported by preliminary SCF and MNDO calculations.

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تاریخ انتشار 2006